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Chemistry II

Code 13405
Year 1
Semester S2
ECTS Credits 6
Workload PL(30H)/T(30H)
Scientific area Biochemistry
Entry requirements Not applied.
Mode of delivery Face-to-face
Work placements N/A
Learning outcomes This course unit aims to provide basic notions of:
-Chemical equilibrium in acid-base, precipitation and oxidation-reduction reactions, including electrochemical cells;
-Relevant methods (classical and modern) of chemical analysis;
-Organic chemistry, organic functional groups, nomenclature, symmetry and stereochemistry;
-Spectroscopic methods (ultraviolet, infrared, nuclear magnetic resonance) and mass spectrometry.
The student should:
1. Classify the different types of chemical reactions, quantitatively analyse chemical equilibrium using classical and modern methods of analysis and perform electrolysis;
2. Recognize organic functional groups, name simple organic molecules, analyse their symmetry and stereochemistry and determine molecular structure with spectroscopic methods;
3. Perform unit operations in the laboratory and perform simple chemical calculations.
Syllabus 1 Chemical Equilibrium 1.1 Thermodynamics; Mass and charge balances 1.2 Acid-base reactions: Brönsted-Lowry definition; pH calculations; Henderson-Hasselbalch equation 1.3 Precipitation reactions: solubility; effect of pH, temperature and common ion 1.4 Redox reactions: oxidants and reducers; balancing equations 1.5 Volumetric methods: acid-base, precipitation and redox; Indicators 1.6 Electrochemistry: electrodes; electrochemical cells; Faraday's law
2 Organic Chemistry and Spectroscopy 2.1 Functional groups and nomenclature 2.2 Stereochemistry: configurational and conformational isomers 2.3 Infrared: vibrations; spectra 2.4 Nuclear magnetic resonance: nuclear spin; 1H-NMR and 13C-NMR; chemical shift 2.5 Mass spectrometry: base, isotope and molecular peak 2.6 Visible ultraviolet: electronic transitions; chromophores

Practical classes: laboratory work (unitary techniques, classical and instrumental methods of analysis) and resolution of exercises on theoretical content.
Main Bibliography 1. Raymond Chang, Jason Overby, “Chemistry”, 13ª ed., McGraw-Hill Education, New York, 2019
2. Skoog D. A., West D. M., Holler F. J., Crouch S. R. "Fundamentals of Analytical Chemistry", Brooks/Cole Cengage Learning, England, 2014.
3. Peter Atkins, Julio de Paula, “Physical Chemistry”, 9th ed, W. H. Freeman and Company New York, 2010
4. Peter Atkins, Julio de Paula, "Physical Chemistry for the Life Sciences", 2nd Ed, W. H. Freeman and Company, New York, 2011
5. Solomons T. W. G., Fryle C. B., Química Orgânica, Vol. 1 e 2, 10ª ed., LTC Livros Técnicos e Científicos Editora S. A.: Rio de Janeiro, 2012.
6. L. S. Campos, M. Mourato, “Nomenclatura de Compostos Orgânicos”, 2ª ed, Escolar Editora, Lisboa, 2000
Teaching Methodologies and Assessment Criteria The teacher explains the concepts of Chemistry, and the theoretical classes are integrated with practical and/or laboratory classes, in order to become participatory classes, with a view to imparting knowledge in an integrated, not dispersed way, leading students to build and to correlate different facts through the discussion of concrete issues and problems. The evaluation will be continuous, through tests about the topics covered in theoretical and practical/laboratory classes, and through evaluation of the overall laboratory performance (which includes preparation of the work to be carried out, results and discussion of the same, and attitudes in classes and laboratory performance).
Language Portuguese. Tutorial support is available in English.
Last updated on: 2024-03-07

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