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Syllabus |
Properties of real gases: Equations of state; Principle of corresponding states
Thermodynamics: conservation of energy, internal energy, heat, work, heat capacity and enthalpy; Applications of the 1st and 2nd laws of real systems; Maxwell Relations; Entropy and Gibbs free energy
Thermochemistry: Internal energy and reaction enthalpy; Hess's and Kirchoff's laws; Calorimetric measurements of enthalpy and internal energy
State changes: Phase stability; Phases diagram; Phase rule; Binary mixtures; Molar partial quantities; Colligative properties; Mixtures of volatile liquids; Vapor pressure/composition, boiling temperature/composition diagrams
Chemical Equilibrium: Gibbs energy and thermodynamic equilibrium constant. Acid-base balance: thermodynamic and apparent acidity constants; amphiprotic systems; pH and speciation
Electrochemical equilibrium: ion migration; types of electrochemical cells; redox potential
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Main Bibliography |
P. Atkins, J. de Paula and J. Keeler, Atkins’ Physical Chemistry, 11th Ed., Oxford University Press, 2018
E. G. Azevedo, Termodinâmica Aplicada, 4ª Ed., Escolar Editora, 2018
E. G. Azevedo, Manual de Exercícios de Termodinâmica Aplicada, Escolar Editora
J. M. Smith, Davis H. C. Van Ness, M. M. Abbott, M. T. Swihart, Introduction to chemical engineering thermodynamics, 8th Ed., McGraw-Hill Education, 2018
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